Recent progress in silicon-based solid-state solar cells

Abstract

ABSTRACTSilicon (Si)-based solar cells constitute about 90% of the photovoltaic (PV) market, and a drastic reduction in module cost and significant improvement in PV performance have been observed since its first inception in 1941. This article aims to present the comprehensive review of prominent advancements enacted in Si solar cells after the year 2000. Monocrystalline Si solar cell has been the matured technology with the record efficiency (η) of 26.6% achieved so far. As the drive to push η around 30% Schokley–Quiesser limit is foreseeable in the near future, PV community is actively striving to fabricate efficient yet cost-effective devices. Polycrystalline Si solar cells contain small-sized grains, and efforts are underway to enhance the η beyond 21.9% by controlling the recombination at grain boundaries, optimising the passivated interfaces and deposition process. Thin-film amorphous Si technology proffers low-cost fabrication process and η of 13.6% has been recorded for a multijunction solar cell. Employment of sophisticated nanowire-based light trapping schemes and dopant-free carrier-selective layers along with the development of hybrid solar cells of organic and Si materials are among the emerging research trends for Si solar cells.