Abstract

A large number of two-dimensional (2D) monoelemental materials with huge application potentials have been developed, since graphene was reported as a monoelemental material with unique properties. As cousins of graphene, 2D group-V elemental monolayers have gained tremendous interest due to their electronic properties with significant fundamental bandgap. In this review, we extensively summarize the latest theoretical and experimental progress in group-V monoelemental materials, including the latest fabrication methods, the properties and potential applications of these 2D monoelementals. We also give a perspective of the challenges and opportunities of 2D monoelemental group-V monolayer materials and related functional nanodevices.

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