Recent developments in thermoelectric materials

Abstract

Efficient solid state energy conversion based on the Peltier effect for cooling and the Seebeck effect for power generation calls for materials with high electrical conductivity σ, high Seebeck coefficient S, and low thermal conductivity k. Identifying materials with a high thermoelectric figure of merit Z(= S2σ/k) has proven to be an extremely challenging task. After 30 years of slow progress, thermoelectric materials research experienced a resurgence, inspired by the developments of new concepts and theories to engineer electron and phonon transport in both nanostructures and bulk materials. This review provides a critical summary of some recent developments of new concepts and new materials. In nanostructures, quantum and classical size effects provide opportunities to tailor the electron and phonon transport through structural engineering. Quantum wells, superlattices, quantum wires, and quantum dots have been employed to change the band structure, energy levels, and density of states of electrons, and have led to improved energy conversion capability of charged carriers compared to those of their bulk counterparts. Interface reflection and the scattering of phonons in these nanostructures have been utilised to reduce the heat conduction loss. Increases in the thermoelectric figure of merit based on size effects for either electrons or phonons have been demonstrated. In bulk materials, new synthetic routes have led to engineered complex crystal structures with the desired phonon-glass electron-crystal behaviour. Recent studies on new materials have shown that dimensionless figure of merit (Z ×temperature) values close to 1·5 could be obtained at elevated temperatures. These results have led to intensified scientific efforts to identify, design, engineer and characterise novel materials with a high potential for achieving ZT much greater than 1 near room temperature.