Abstract
Based on the structural features of Hofmann-type clathraces M(NH 3) 2M'(CN) 4 · 2G (M = a divalent metal in six-coordination, M' = a divalent metal in square-planar coordination, G = a small aromatic guest molecule), several series of the analogous clathrates have been derived by appropriate replacements of the host moieties. These clathrates are designated with a general formula Cd (diam)M'(CN) 4 · n G where diam refers to diammine, an ambident diamine or monoethanolamine (mea), or a pair of unidencate mea's, M'(CN) 4 is a square-planar or a tetrahedral tetracyanometallate(II), and G is a small aromatic guest molecule. The number of guest molecules, n , varies stepwise from 2 through 3 2 to 1 depending on the bulkiness of diam ligand which builds up the host structure. Their structural features are discussed on the two- and three-dimensional networks of the metal complex hosts. The historical background is also reviewed briefly.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
