Abstract

Abstract The chemistry of the most recent years of binary nitrogen-halogen species is discussed in four chapters. Chapter I focusses on nitrogen-fluorine compounds, including NF3 N2F4 N2F2 and the NF4 + N2F3 + N2F+ and NF2+ cations. In Chapter II the trihalogeno nitrides NX3 (X = Cl, Br, I) and the NCl4 + cation are described and the likely existence of heavier analogues NBr4 + and NI4 + is discussed. Whereas all halogen azides XN3 (X = F, Cl, Br, I) are summarized in Chapter III, the ionic nitrogen iodine species I2N2 + I(N3)2 + I2N3 − and I(N3)2 − are comprised in Chapter IV.

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