Recent Developments in Conjugated Polymer Based Plastic Solar Cells

Abstract

Recent developments on photovoltaic elements based on solid state composites of conjugated, semiconducting polymers mixed with buckminsterfullerene are reviewed. The photo-induced charge transfer from donor-type semiconducting conjugated polymers onto acceptor-type conjugated polymers or acceptor molecules such as buckminsterfullerene is reversible, ultrafast (within 100fs) with a quantum efficiency approaching unity, and the charge separated state is metastable (up to ms at 80 K). This phenomenon of photoinduced electron transfer leads to a number of potentially interesting applications which include, among others, sensitization of the photoconductivity, reverse saturable absorption (optical limiting), and photovoltaic phenomena. Recent studies on the realization of photovoltaic elements with 3% power conversion efficiency are reported.