Abstract
A critical overview is given of the principle and practice of modern mechanochemical processes for the preparation and design of high value-added materials. Some fundamental principles of bridging bond formation under mechanical stressing are given. The importance of the low coordination states and effects of symmetry disturbance of crystal and ligand fields are emphasized. Several successful application examples are displayed, stemming from inorganic complex oxides for electronic and construction materials, bioceramic materials to metal organic coordination compounds.
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