Abstract
From the point of the view of the synthetic efficiency, the concept ‘step economy’ was required in total synthesis of natural product. Recently, versatile gold-catalyzed cascade reactions have been developed, and relating reports on practical applications in total synthesis has increased. This digest focuses and summarizes the gold-catalyzed reaction cascades in natural product synthesis during last five years with brief discussion on the reaction mechanism of the key gold-catalyzed cascade transformations.
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