Abstract
AbstractAllyl alcohol compounds are widely used structural units. In recent years, considerable attention has been devoted to exploring the migration reactions of allyl alcohols via semipinacol or neophyl rearrangements, and so on, providing an attractive and powerful strategy for obtaining various important carbonyl compounds.However, to date, no review has been published that summarizes the significant advances in the preparation of functionalized carbonyl compounds using these migration rearrangement reactions. In this paper, the latest progress in the use of allyl alcohols as flexible synthons involving group migration is introduced, and the reaction scopes, limitations, and some of the mechanisms are also discussed.magnified image
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