Abstract

AbstractAn overview of our work in the areas of polynitrogen and high‐nitrogen and high‐oxygen chemistry is given. Areas of interest include the synthesis and characterization of novel polynitrogen ions, such as N5+ and N5−. Efforts are discussed to combine the N5+ cation with energetic counter‐ions, such as N3−, NO3−, ClO4−, B(N3)4− and P(N3)6−. In the area of high‐oxygen carriers, complex nitrato anions were successfully combined with tetrazolium cations to yield CO/H2O balanced ionic liquids of interest for liquid monopropellants.

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