Abstract
AbstractThis review article outlines the literature from 2022 to 2024 covering developments in SF5 chemistry. Recent synthetic methodologies of SF5-containing building blocks are reported. These methods include the synthesis of SF5Cl and its use in pentafluorosulfanylation reactions and oxidative fluorination reactions. Moreover, the reactivity of SF5-alkynes as versatile platform to access new SF5-compounds is described. Finally, the effects of the SF5 moiety are highlighted according to its application in different fields, such as biological/medicinal chemistry, catalysis, and material sciences.1 Introduction2 Access to SF5-Containing Building Blocks2.1 By Means of SF5Cl2.1.1 Generation of SF5Cl2.2 By Means of Oxidative Fluorination2.3 By Means of SF5-Alkynes2.4 Other Miscellaneous Aromatic and Aliphatic SF5-Compounds3 Applications3.1 Medicinal and Biological Chemistry3.2 Material Science3.3 Catalysis4 Conclusion
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