Abstract
This brief review article describes developments in the aza-Claisenrearrangement over the last nine years. In this article, the emphasishas been given to the various aspects of the aza-Claisen- rearrangement,especially metal-mediated stereoselective transformation, zwitterionicaza-Claisen rearrangement and microwave-assisted aza-Claisen rearrangement. 1 Introduction 2 Definition and Overview 3 Thermal Aza-Claisen Rearrangement 4 Catalysis of the Aza-Claisen Rearrangement 4.1 Catalysis by Boron Reagents 4.2 Catalysis by Palladium Reagents 4.3 Catalysis by Gold Salts 4.4 Catalysis by Ruthenium Salts 4.5 Catalysis by Zinc(II) Chloride 5 Zwitterionic Aza-Claisen Rearrangement 6 Microwave-Assisted Aza-Claisen Rearrangement 7 Miscellaneous 8 Conclusions
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