Abstract
Within this review, recent developments in the field of C(sp<sup>3</sup>)–H activation catalyzed by palladium are discussed. Both intra- and intermolecular reactions towards carbon–carbon and carbon–heteroatom bonds are covered. In the case of intramolecular reactions, asymmetric versions are reported as well. The main focus of this review is literature of the last five years until late 2013. 1 Introduction 2 Intramolecular C(sp<sup>3</sup>)–H Activation 2.1 Carbon–Carbon Coupling 2.2 Carbon–Heteroatom Coupling 2.3 Stereoselective Reactions 3 Intermolecular C(sp<sup>3</sup>)–H Activation 3.1 Carbon–Carbon Coupling 3.2 Carbon–Heteroatom Coupling 4 Conclusion and Outlook
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