Recent advances in nanoflowers: compositional and structural diversification for potential applications.

Abstract

In recent years, nanoscience and nanotechnology have emerged as promising fields in materials science. Spectroscopic techniques like scanning tunneling microscopy and atomic force microscopy have revolutionized the characterization, manipulation, and size control of nanomaterials, enabling the creation of diverse materials such as fullerenes, graphene, nanotubes, nanofibers, nanorods, nanowires, nanoparticles, nanocones, and nanosheets. Among these nanomaterials, there has been considerable interest in flower-shaped hierarchical 3D nanostructures, known as nanoflowers. These structures offer advantages like a higher surface-to-volume ratio compared to spherical nanoparticles, cost-effectiveness, and environmentally friendly preparation methods. Researchers have explored various applications of 3D nanostructures with unique morphologies derived from different nanoflowers. The nanoflowers are classified as organic, inorganic and hybrid, and the hybrids are a combination thereof, and most research studies of the nanoflowers have been focused on biomedical applications. Intriguingly, among them, inorganic nanoflowers have been studied extensively in various areas, such as electro, photo, and chemical catalysis, sensors, supercapacitors, and batteries, owing to their high catalytic efficiency and optical characteristics, which arise from their composition, crystal structure, and local surface plasmon resonance (LSPR). Despite the significant interest in inorganic nanoflowers, comprehensive reviews on this topic have been scarce until now. This is the first review focusing on inorganic nanoflowers for applications in electro, photo, and chemical catalysts, sensors, supercapacitors, and batteries. Since the early 2000s, more than 350 papers have been published on this topic with many ongoing research projects. This review categorizes the reported inorganic nanoflowers into four groups based on their composition and structure: metal, metal oxide, alloy, and other nanoflowers, including silica, metal-metal oxide, core-shell, doped, coated, nitride, sulfide, phosphide, selenide, and telluride nanoflowers. The review thoroughly discusses the preparation methods, conditions for morphology and size control, mechanisms, characteristics, and potential applications of these nanoflowers, aiming to facilitate future research and promote highly effective and synergistic applications in various fields.