Abstract
Linear thermodynamic function relationships (LTFR) comprise the following three subjects: (1) linear free energy relationships (LFER), (2) linear enthalpy relationships (LER), and (3) linear entropy relationships (LSR). LFER have been extensively studied in the past few decades and cover a wide range of areas in chemistry. We have recently explored the subject of LER and LSR and found explicitly the existence of these linear energy relationships. The present article is devoted to a review of the most recent advances of these three linear relationships studied in our laboratory and finds that the compensation law in solution chemistry can be extended to this area.
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