Recent advances in electrochemical functionalization using diazonium salts.

Abstract

Arenediazonium salts have gained attention in the scientific community due to their numerous synthetic applications. In the traditional method of dediazoniation of arenediazonium salts, the requirements for toxic oxidants and costly catalysts affect their cost-effectiveness and sustainability. However, recent advances in synthetic organic electrochemistry allow for the in situ reduction of arenediazonium salts, affording different functionalizations under mild reaction conditions and with a shorter reaction time. Herein, we report advances up to now of facile organic electrochemical syntheses using arenediazonium salt precursors that avoid the use of hazardous reductants.