Abstract
AbstractElectricity generation and chemical production are both critical cornerstone for modern society. Integrating electricity output and high value chemical production in an electrochemical system is highly attractive both environmentally and sustainably. In this review, we summarize the recent advances in the development of these multifunctional devices (electrocatalytic flow batteries) that could generate both electricity and high value chemicals through rational coupling of half‐electrode reactions, covering the basic principles, device configurations, and applications. We also discuss the current challenges and suggest potential research directions.
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