Abstract

AbstractGold nanoparticles (AuNPs) exhibit high catalytic activity as catalysts and have potential applications in biomedicine. To prevent the aggregation of colloidal AuNPs, the stabilizers including organic small molecules, organic ligands, inorganic ligands, and polymers, are necessary to be added in the synthesis of colloidal AuNPs. Among these stabilizers, amphiphilic polymers have attracted significant attention from scientists in the development of polymerization and modification methods. To date, numerous efforts are employed to develop amphiphilic polymers as the stabilizers of colloidal AuNPs but are not well‐summarized yet. In this review, four parts (amphiphilic linear polymers, amphiphilic graft polymers, amphiphilic hyperbranched polymers, and amphiphilic dendrimers) according to the polymer architectures will be discussed. Comprehensive understanding of amphiphilic polymers that are used for stabilizing colloidal AuNPs is provided.

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