Abstract

Over the last decade, acoustic methods, including acoustic emission (AE) and ultrasonic testing (UT), have been increasingly deployed for process diagnostics and health monitoring of electrochemical power devices, including batteries, fuel cells, and water electrolysers. These techniques are non-invasive, highly sensitive, and low-cost, providing a high level of spatial and temporal resolution and practicality. Their application in electrochemical devices is based on identifying changes in acoustic signals emitted from or propagated through materials as a result of physical, structural, and electrochemical changes within the material. These changes in acoustic signals are then correlated to critical processes and the health status of these devices. This review summarises progress in the use of acoustic methods for the process and health monitoring of major electrochemical energy conversion and storage devices. First, the fundamental principles of AE and UT are introduced, and then the application of these acoustic techniques to electrochemical power devices are discussed. Conclusions and perspectives on some of the key challenges and potential commercial and academic applications of the devices are highlighted. It is expected that, with further developments, acoustic techniques will form a key part of the suite of diagnostic techniques routinely used to monitor electrochemical devices across various processes, including fabrication, post-mortem examination and recycle decision support to aid the deployment of these devices in increasingly demanding applications.

Highlights

  • In the last few decades, extensive attention has been paid to weaning global energy production away from 7 fossil fuels to address environmental sustainability and energy security concerns

  • 145 A typical acoustic emission (AE) monitoring setup is shown in Figure 1, consisting of a sensor, preamplifier, filter, amplifier, 27 146 alongside data acquisition and signal processing units

  • 632 that the amplitude of the input ultrasonic pulse is weakened as the cell is cycled, attributed to the degradation 53 54 633 of interfaces inside the cell caused by electrode expansion, gas evolution, or stress developing along the

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Summary

Introduction

48 60 sources, crucial to the prospect of a renewable hydrogen economy [15,25] Taken together, this portfolio of 61 devices are well suited for integration into energy production for domestic, industrial, automotive and 50 51 62 consumer electronics applications. The ultrasonic testing (UT) technique, on the other hand, is an 97 active technique in which externally generated acoustic signal is introduced and propagated through the 53 54 98 material to study the internal structure and processes. Acoustic emission (AE) is a passive non-destructive technique whereby transient elastic waves are 112 generated by the rapid release of energy from a localised source or sources within a solid material [55]. 115 hertz) to ultrasonic frequencies in the megahertz range These stress waves propagate to the surface and can 32 be detected and converted to electrical signals using piezoelectric sensors [54,56]. 21 143 [3,65] and oxygen reduction [66]

Instrumentation
Theory and Implementation
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52 931 5.0 Conclusion
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