Recent Advances and Applications of Inorganic Electrides.

Abstract

Electrides, accommodating excess electrons in lattice voids as anions, have attracted considerable attention in both fundamental research and application development because of their interesting properties, such as ultralow work functions, high electronic mobility, high catalytic activity, and anisotropic electronic and optical properties. Recently, much research progress has been made in both types and applications of inorganic electrides because of the high stability. In this Perspective, we aim to summarize the recent development of inorganic electrides discovered and proposed by experiment and theoretical calculations, highlighting the main applications, including catalysis, metal-ion batteries, superconductivity, magnetism, and organic light-emitting diodes. We provide insights into the role of anionic electrons in electrides playing in the stability and properties. Finally, the problems, challenges, and opportunities are presented, which provide an outlook for future research.