Reassessing water slippage in hydrophobic nanostructures.

Abstract

Reported data of measured slip lengths in nanostructures span several orders of magnitude, from a few nanometers to tens of micrometers. Small roughness on surfaces caused by structural defects or thermal fluctuations dramatically reduces slippage. Tiny bubbles entrapped on rough surfaces can also affect slippage. We used an asymptotic solution and a high density-ratio pseudopotential lattice Boltzmann model to systematically study the drag resistance of a rough surface with attached bubbles. As bubbles nucleate and grow, drag resistance is slightly reduced until the tri-phase contact line reaches the edges of roughness, where bubbles with small angles substantially reduce drag resistance. As bubbles grow to become a continuous gas layer on the surface, the drag resistance greatly decreases. However, the interface deformation from flat to curved shape greatly hinders liquid flow, and the vortex structures cause a wave-like fluctuation in the effective slip length. This finding sheds light on the controversies of reported large variations in the slip length of super-hydrophobic surfaces in nanostructures, e.g., carbon nanotubes.