Abstract
Internally-bridged octaphyrin(1.1.1.1.1.1.1.1) underwent a rearrangement to meso-meso linked porphyrin dimer as a new metamorphosis. Extensive examination suggests that hydride-addition is a key step for the rearrangements to afford thermodynamically more stable porphyrin framework. Further, β-tetrabromo[36]octaphyrin was transformed to meso-meso, β-β, β-β triply linked porphyrin dimer via a similar mechanism combined with Pd-mediated reductive homocoupling.
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