Abstract
The literature data on the rearrangements of vinyl cationoid intermediates arising in the solvolysis of various vinylderivatives and in the addition of cationoid reagents to the triple bond are examined and the differences between therearrangements of vinyl cations and those of the "usual" saturated carbonium ions are demonstrated. The influence ofthe structure of vinyl cationoid intermediates on the rate and mode of rearrangements of various types (the migrationof alkyl and aryl groups, shifts via the double bond and to a double bond, and higher-order shifts) are discussed. The bibliography includes 87 references.
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