Rearrangement of twin variants in ferromagnetic shape memory alloy–polyurethanecomposites studied by stroboscopic neutron diffraction

Abstract

The use of ferromagnetic shape memory alloy (FSMA) particles as fillers in polymericmatrix composites has been proposed for vibration damping. The large pseudo-plasticrecoverable deformation of the FSMA particles due to the rearrangement of twin variantscan dissipate a large amount of energy, both under compression and tension. Thecomposites studied are made by mixing particles of NiMnGa with a polyurethane matrix.A magnetic field is applied to the composite while the matrix sets, to achieve a strong [112]texture in the field direction. In situ strobed neutron diffraction measurements were carriedout while the composites were subjected to a cyclic deformation. They show that theintensity of certain peaks varies during the deformation cycle. All the peaks that showthis behavior can be grouped into pairs that stem from a single austenitic peak.The (020) and (112) martensite peaks correspond to the splitting of the (220)austenite peak, and the intensity of one increases as that of the other decreases. Theneutron measurements show directly that there is a change in the texture of thecomposite during the stress cycle applied to the composite and confirm that thelarge mechanical loss observed in the stress–strain cycles is in good part due tothe rearrangement of twin variants in the FSMA filler used in the composites.