Abstract
1. One-step outlying oxidative chlorination of alkanesulfonamides by the action of the Na2S2O8-CuCl2 system via intermediate sulfonamidyl radicals gives 3- and 4-chloroalkanesulfonamides. 2. Rearrangements of sulfonamidyl radicals with H atom migration from the sulfonyl segment predominates over rearrangement with H atom migration from the amide segment.
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Schedule a callMore From: Bulletin of the Academy of Sciences of the USSR, Division of chemical science
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