Abstract
A strategy was developed to obtain from acetylenedicarboxylic acid either an acetylenedicarboxylate-based ZrIV metal-organic framework (MOF) with fcu topology or a halo-functionalized-MOF-801 through in situ ligand hydrohalogenation. The new materials feature exceptionally high hydrophilicity and CO2 /H2 adsorption energetics. The acetylenedicarboxylate linker and its functionalizable triple-bond discloses its potential in the engineering of microporous materials with targeted properties.
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