Realizing negative index of refraction in an ensemble of ground-state polar molecules with lasers

Abstract

We propose a coherent optical method for creating negative refractive index (NRI) for a gaseous ensemble of ground-state polar molecules possessing both permanent electric and magnetic moments. Exploiting the pure rotational transition between the two lowest rotational levels of the ground vibrational state one can generate two dressed states of mixed parity using a microwave laser. These dressed states are then used as the two lower states of a Λ-type three-level scheme using two infrared lasers to couple them to another ro-vibrational level in the ground-state manifold. One of the infrared lasers is used as a weak probe and the other as a control field with a fixed detuning. We take into account local-field effects on the dielectric response of the medium at the probe frequency in terms of Clausius–Mossoti relation. We extract magnetic response out of purely dielectric response and calculate the magnetic permeability of the medium in terms of dielectric susceptibility. Our results show that there is a small frequency window near the two-photon resonance where both electric permittivity and magnetic permeability are negative with vanishingly small absorption. The figure of merit for the medium is shown to exceed unity. We interpret our results in terms of the proximity of EIT and quantum interference. We discuss the possible realization of our method using cold polar molecules that are recently experimentally produced.