Real-space renormalization-group treatment of the Maier-Saupe-Zwanzig model for biaxial nematic structures.

Abstract

The Maier-Saupe-Zwanzig model for the nematic phase transitions in liquid crystals is investigated in a diamond hierarchical lattice. The model takes into account a parameter to describe the biaxiality of the microscopic units. Also, a suitably chosen external field is added to the Hamiltonian to allow the determination of critical parameters associated with the nematic phase transitions. Using the transfer-matrix technique, the free energy and its derivatives are obtained in terms of recursion relations between successive generations of the hierarchical lattice. In addition, a real-space renormalization-group approach is developed to obtain the critical parameters of the same model system. Results of both methods are in excellent agreement. There are indications of two continuous phase transitions. One of them corresponds to a uniaxial-isotropic transition, in the class of universality of the three-state Potts model on the diamond hierarchical lattice. The transition between the biaxial and the uniaxial phases is in the universality class of the Ising model on the same lattice.