Abstract
Nickel(O) complex moieties with a high electron density at the central atom are able to yield stable complexes with many aromatic aldehydes. 1H NMR spectroscopic data give evidence about olefin-like bonding of the aldehyde group and indicate a high charge transfer. Chelate ligands like tetramethylethylenediamine yield stable complexes of the composition (TME)NiL (L = aldehyde, benzil, α,β-unsaturated carbonyl compounds). Some reactions and properties of typical mixed ligand complexes are described.
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