Reactivity Test of Ni-based Catalysts Prepared by Various Preparation Methods for Production of Synthetic Nature Gas

Abstract

In this study, the Ni-based catalysts for the production of synthetic natural gas were prepared by various preparation methods such as the co-precipitation, precipitation, impregnation and physical mixing methods. The ranges of the reaction conditions were the temperatures of 250~, /CO mole ratio of 3.0, the pressures of 1 atm and the space velocity of 20000 . It was found that the catalyst prepared by precipitation method had higher CO conversion than the catalyst prepared by co-precipitation method. While the catalyst prepared by precipitation method had the formation of NiO structure, the catalyst prepared by co-precipitation method had the formation of structure. It was confirmed that Ni-based catalyst prepared by the physical mixing method had the lowest CO conversion because it was deactivated by the production of during the methanation. As a result, it was shown clearly that Ni-based catalysts prepared by impregnation method expressed the highest catalytic activity in CO methanation.