Abstract

Siliceous materials such as quartz and basic or devitrified volcanic rocks, which are not likely sources of active pozzolan, become highly reactive when ground to ultrafine powders. If grinding is sufficiently prolonged an upper limit of activity is attained, beyond which continued increase in surface area does not produce any further general increase in pozzolanic reactivity. With widely differing types of siliceous material the upper limit of pozzolanic reactivity attained at very high surface areas tends to be the same in all cases, regardless of whether the mineral powders would be classed as pozzolanic, weakly pozzolanic, or nonpozzolanic when ground to the usual fineness specified for pozzolans. These observations can be explained by the presence of a disturbed layer of highly reactive material which is formed on the surface of siliceous mineral particles as a result of prolonged grinding .

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