Abstract
The three-coordinate iron(II) NHC complexes [(IPr)Fe(N'')2] (1) and [(I(t)Bu)Fe(N'')2] (3) (N'' = N(SiMe3)2) react with PhSeH or LiSePh to give the iron(II) selenolates [(IPr)Fe(N'')(SePh)] (6) and [I(t)Bu(H)][(aI(t)Bu)Fe(SePh)3], [I(t)Bu(H)][7], with complex 7 containing an abnormal NHC ligand.
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