Reactivity of the iron porphyrin Fe(TPP)(NO) with excess NO. Formation of Fe(TPP)(NO)(NO2) occurs via reaction with trace NO2.

Ivan M Lorković,Peter C Ford

doi:10.1021/ic9910413

Reactivity of the iron porphyrin Fe(TPP)(NO) with excess NO. Formation of Fe(TPP)(NO)(NO2) occurs via reaction with trace NO2.

Ivan M Lorković, Peter C Ford

https://doi.org/10.1021/ic9910413

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Journal: Inorganic chemistry	Publication Date: Jan 27, 2000
Citations: 60

Affiliation: University of California, Santa Barbara

#Excess NO #Tetraphenylporphyrinato Dianion + Show 5 more

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Abstract

Fe(TPP)(NO) (TPP = tetraphenylporphyrinato dianion) does not react observably with excess NO in organic solvents at ambient pressure and temperature; however, adventitious NO2 rapidly leads to the nitrosyl nitro product Fe(TPP)(NO)(NO2), which is labile toward loss of NO.

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