Abstract
The reaction of heteroleptic silylene LSiNPh2 [L = PhC(NtBu)2] with diazobenzene afforded product 6. This involves one o-C–H bond activation at one of the phenyl groups of diazobenzene and migration of this hydrogen atom from the phenyl ring to one of the nitrogen atoms, which leads to the formation of the new C–Si and N–Si bonds. The reaction of benzylidineaniline with LSiNPh2 results in the oxidative addition of the three-membered silaaziridine derivative 7. Compounds 6 and 7 were fully characterized by elemental analysis, multinuclear NMR spectroscopy, and EI-MS spectrometry. The molecular structures of compounds 6 and 7 were established unequivocally by single-crystal X-ray structural analysis.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
