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Abstract
B-H bond activation: Depending on the stability of the borane adduct, Li/Cl carbenoids react with BH3⋅LB either under B-H bond activation at the carbenic carbon center or under carbene dimerization. The B-H bond activation proceeds in a stepwise fashion with the nucleophilic attack of the Li/Cl carbenoid at BH3⋅LB as the crucial step determining the course of the reaction.
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