Abstract
AbstractReaction of metallophosphide anions [(CO)xM′PPh2]− (M′ = Cr, Fe) with neutral tricarbonyl(η6‐fluoroarene)chromium and cationic (η6‐arene)tricarbonylmanganese complexes give rise to the formation of dinuclear complexes. These complexes are obtained either by substitution of the fluoride anion in the (arene)chromium complexes, or by addition to the ring in the (arene)manganese complexes. The X‐ray structure of one homodimetallic (Cr−Cr) complex was obtained and compared with its solution structure. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)
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