Abstract
Reaction at the Zr centre in (η5-C4Me4P)2ZrCl2 (1) is exemplified by the reaction with MeLi or PhLi to give (η5-C4Me4P)2ZrR2, with R = Me or Ph. Complex 1 can also react through the lone pair on the P atom with L2M(CO)n to give chelates (CO)nM(μ-η5,η1-C4Me4P)2ZrCl2 where M(CO)n = Fe(CO)3 or W(CO)4, in which a new type of bridging η5-ligand is present. The crystal structure of (CO)3Fe(μ-η5,η1-C4Me4P)2ZrCl2 is described.
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