Abstract
The stannylene {2-[(CH 3) 2NCH 2]C 6H 4} 2Sn ( 1) was reacted with oxygen, sulfur, selenium, tellurium, and carbon disulfide. The reactions with heavier chalcogens led to the rapid formation of 1:1 dinuclear adducts which were characterized by elemental analysis, ESI-MS measurements, 1H NMR spectroscopy, and structurally characterized by X-ray diffraction (in the case of reaction products with S 8 ( 3) and Te ( 5)). The reaction of 1 with carbon disulfide and elemental sulfur yields the remarkable compound {{2-[(CH 3) 2NCH 2] 2C 6H 4}Sn} 2(μ 2-S 2C CS 2) ( 3a). The stability and reactivity of compounds 1– 5 were rationalized at DFT/TZ2P level.
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