Abstract
Strongly basic amines react with the ( syn,syn-1,5-dimethylpentadienyl)iron tricarbonyl cation to give ( cis,trans-dienylamine)iron tricarbonyl complexes through an exo attack of the nucleophile on the coordinated pentadienyl group. Weakly basic amines give ( trans,trans-dienylamine)iron tricarbonyl complexes, i.e., the reaction proceeds with geometrical inversion. The stereochemistry of the new complexes has been elucidated by NMR, CD and X-ray analysis.
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