Abstract
Summary The rates of reaction of the radical ions of diethyl fumarate, ethyl cinnamate, stilbene and anthracene, with some organic halides, proton donors and olefins, were measured by cyclic voltammetry. A linear correlation was found between the logarithm of the rate constants and Δ E , the difference in half-wave potential between the electroactive compound and the reactant. Water was an exception, its reactivity is discussed in terms of the charge distribution of the ions.
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