Reactive sulfide dynamic models for predicting metal hazardous in sediments of two northern Egyptian Lakes

Abstract

To track pollution status and bioavailability of Cu, Zn, Cd, Pb, and Ni, the current study's acid-volatile sulfide (AVS) and simultaneously extracted metals (SEM) models were compared to previous studies in Edku and Mariut lakes prior to 8 years. Sediment samples were collected in winter and summer 2019 from the two lakes. Metal pollution is higher in the winter than in the summer, according to SEM/AVS models. Metal toxicity is reported to have increased slightly in both lakes. According to risk quotients (RQSEM-PEL and RQSEM-TEL) the two lakes are moderately polluted. The results of the Fe/AVS ratio were in the range of 6.77 to 226.87 and 2.88 to 36.38 μmol/g for Edku and Mariut lakes, respectively. This indicated that [SEM]/[AVS] ratios overestimate the availability of metals. A positive correlation was reported between total organic matter and ∑SEM (r = 0.74 and 0.39 at p < 0.05) in Mariut and Edku lakes, respectively. Multiple-year SEM-AVS studies are recommended.