Abstract

Catalytic and adsorptive behaviors of montmorillonite to remove methylene blue were investigated. The clay mineral showed high activity for the oxidation of methylene blue in presence of H 2O 2 and on removing the organic substrate through reactive adsorption as evidenced from Electrospray Ionization Mass Spectrometry (ESI-MS) data. Montmorillonite was characterized by atomic absorption, powder X-ray diffractometry, scanning electron microscopy coupled with energy dispersive spectroscopy, infra-red spectroscopy and surface area analyses. Results indicated a highly reactive surface with can be regenerated by H 2O 2, promoting heterogeneous catalytic reaction to oxidize organic compounds from aqueous medium without any previous treatment of the montmorillonite.

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