Abstract
AbstractGeminal diazides are uncommon yet powerful tools in organic synthesis. The chemistry of this class of functional compounds is characterized by quite unusual reactivities, including fragmentations and degradations, along with known reactions of organic azides. This Short Review highlights the major reactivities of various structural units having geminal diazido moieties, and provides an overview on the synthetic opportunities of such compounds.1 Introduction2 Preparation of Geminal Diazides3 Reactivities of Geminal Diazides3.1 α,α-Diazido Carbonyls3.2 1,3-Diketones3.3 Diazidated β-Ketoesters3.4 Diazidated Malonates3.5 Diazidated Malonamides3.6 Miscellaneous Geminal Diazides4 Conclusion
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
