Abstract

Reactivity of ytterbium and magnesium complexes of gallylenes against carbon dioxide and diphenylketene has been assessed. Ytterbium complex of redox-active gallylene [{(dpp-bian)Ga}2Yb(DME)2] (dpp-bian = 1,2-bis[(2,6-diiso-propylphenyl)imino]acenaphthene) on treatment with CO2 gives complex [(dpp-bian)Ga(DME)Me], while the treatment of magnesium-stabilized gallylene[{(dpp-bian)Ga}2Mg(DME)2] with Ph2CCO affords cycloadduct [(dpp-bian)(Ph2CCO)GaMe].

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call