Abstract
Addition of arenediazonium or tropylium salts to Ru(C 2Ph)(L) 2(η-C 5H 5) (L 2 = (PPh 3) 2 or DPPE) gives the corresponding cationic aryldiazovinylidene and cycloheptatrienylvinylidene complexes, respectively; the X-ray structures of the title complexes confirm the presence of the new ligands. The RuC and CC distances are 1.823(9) and 1.34(1) Å for the aryldiazo complex, and 1.848(9) and 1.32(1) Å for the cycloheptatrienyl derivative.
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