Abstract

Chloramine T reacted readily with aliphatic and aromatic thiones, acting as a nucleophilic and as an oxidizing reagent. The non-thioenolizable thiones, thioadamantanone and thiobenzophenone afforded thio-ozonide products. Thiocamphor, however, gave an unsaturated disulphide dimer which on heating underwent a stereospecific Cope-type rearrangement.

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