Abstract
Abstract The reactions of ketone derivatives containing carbon-nitrogen double bond such as oximes (3), N-alkyloximes (nitrones, 11), oxime O-alkyl ethers, phenylhydrazones and semicarbazones with thiocarboxylic acids were studied for the purpose of preparing thioketones. Both 3 and 11 reacted with thiocarboxylic acids to give thioketones in good yields. The reaction did not proceed in the cases of other ketone derivatives, the starting materials being recovered. The reaction of benzophenone oxime with thiobenzoic acid gave thiobenzophenone, dibenzoyl disulfide and ammonium benzoate, while that of benzophenone-N-methylnitrone with thioacetic acid gave thiobenzophenone and N-acetyl-N-methylhydroxylamine. The mechanisms of these reactions are presented.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
