Abstract
Theortho-metallated complex [RhP3Pt] [P=P(OPh)3, P′=P(OC6H4)(OPh)2] was obtained in the reaction of [RhP4]ClO4 with KOH. It reacts easily with proton donors HX (X=ClO4, F, Cl, SCN, or acetylacetonate) to produce complexes [RhP3X] when X is a strong donor. If X is a weaker donor (X=ClO4 or F), pentacoordinate compounds of the type [PhP4X] are formed. [RhP3P′] reacts with acetylacetone (Hacac) to produce [Rh(acac)P2].
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