Reactions of the dicarbonyl complex Re2Cl4(dppm)2(CO)2 with nitriles and isocyanides. Synthesis of [Re2Cl3(dppm)2(CO)2L]n+ (n = 0, 1; L = RCN, RNC) and the structural characterization of [Re2Cl3(dppm)2(CO)2(NCC2H5)]PF6

Abstract

Reactions of the dicarbonyl complex Re2Cl4(dppm)2(CO)2 with nitriles and isocyanides. Synthesis of [Re2Cl3(dppm)2(CO)2L]n+ (n = 0, 1; L = RCN, RNC) and the structural characterization of [Re2Cl3(dppm)2(CO)2(NCC2H5)]PF6