Abstract

Abstract The reactions of cobaltadithiolene complexes bearing phenyl or ester ligands with tetracyanoethylene oxide (TCNEO) result in the formation of dicyanomethylene-bridged complexes, via dicyanomethylide intermediates. Furthermore, the reaction of cobaltadithiolene complex bearing 4-pyridyl ligands produces pyridinium dicyanomethylide complexes in good yields.

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